Oil Drop Trap is Set for a Lone Quark
SLAC . The drip consists of tiny droplets of silicone oil. 7micrometers
in diameter, falling languidly between 2 electrically charged plates while
a CCD video camera records their movements. Robert Millikan applied 85
years ago in his classic measurement of the charge of a single electron.
Martin Perl hoping to find a droplet bearing a still smaller morself of
charge - a quark, a fundamental particles that make up protons and
neutrons.
No free quarks spotted in the first round. QCD theory of the strong
force binds quarks.
/*---------------------------------------------------------------------*/
Tuning a Catalyst for New Plastics
Adding boron to carbon rings lets researchers "tune", or adjust, the
electronic behavior of this catalyst.
If plastics are big business, the catalysts that create many of them
are the keys. Indeed without them, plastic production, currently worth
hundreds of bbillions of dollars annually, would be hobbled because there
would be no way to link the small chemical building blocks from which
plastics are made. One breed of catalysts that link building blocks
called alpha-olefins typically employ rings of carbons to do their jobs.
But now researchers, bby inserting bboron atoms into the carbon rings,
are developing a new class of catalysts - an possibly whole new classes
of polymers too.
3/6/96 issue of journal of the american chemical society , a group of
chemists at the University of rochester in New York and the university
of Michigan in Ann Arbor report that boron atoms, in combination with
different chemical groups attached to them, can change how electrons are
distributed throughout the catalyst molecule. That should give scientists
a new way to "tune" , or change, the catalyst's electronic properties.
Because those properties help determine which olefins the catalyst will
link together and how they assemble, increased tunability should lead to
new types of polymers, possibly with different molecular weights or
densities, says Guillermo Bazan, one author of the report. Just what
those polymers will look like and how they will behave "is impossible to
predict", he says. But although the researchers have not yet created a
catalytic choir, just one compound humming a single note, it performs as
well as current catalysts, and thus is "a promising first step," says
Francis Timmers, a catalysis expert at the Dow Chemical Company's Central
REsearch LAboratories in Midland, Michigan.
Catalysts of this type, known as metallocenes, typically consist of a
single metal atom, such as zirconium, surrounded by a pair of all- carbon
rings, which are in turn linked to other chemical groups. One end of the
growing polymer chain binds near the metal, while together the rings and
dangling groups control access of the olefin building blocks to that
interior complex, forcing them to bind in one preferred orientation to the
end of the chain. Bazan and his colleagues found that adding boron atoms
to the rings shakes things up a bit. Boron is electron-hungry and tends
to borrow electrons from other atoms in the catalyst, atoms either in the
surrounding chemical groups or the core atom itself. That change in the
distribution of electrons in the catalyst molecule is what alters the
catalyst's interaction with the olefin building blocks. Along with Arthur
Ashe and his colleagues at Michigan, Bazan and his Rochester group found
they could control this electron distribution by adding specific groups to
the borons. The researchers linked the borons to nitrogen-containing
amine groups and then inserted the borons into a pair of carbon rings
surrounding a zirconium atom. as a result of this configuration, each
boron grabbed a pair of electrons from the nearby nitrogen, leaving those
around the metal undistrubed. That made the catalyst behave just like an
ordinary catalyst with all-carbon rings and produce polyethlene and other
polymers as effectively as conventional metallocene catalysts.
The researchers next plan to replace the amines with carbon-based
phenyl rings. These rings should not give up electrons to the boron
atoms, which should therefore scavenge electrons from the zirconium -
altering the metal's electronic and catalytic behavior. If so, polymer
catalysts may soon be singing some new tunes.
/*---------------------------------------------------------------------*/
Isolated Neutron Stars
INSs are only active for a fraction of their lifetime 10^10 years.
Violent and short nonthermal phase they are visible as radio pulsars for
10^6.5 years. They cool after being born in a supernova, neutron stars
maintain a surface temperature of > 10^5K for the same time period. Thus
about 10^-3 of the INS population might be deted either as radio pulsars
or through their thermal surface emission, assuming they are sufficiently
hot and luminous to be picked up by the current generation of xray, UV and
optical telescopes, which only sample a small volume of our galaxy. When
the radio mechanism fades away and their surface temperature drops, the
INss become invisible and just sit there, making up a fraction of the
galactic dark baryonic matter. They can be revived by a companion from
which they start accreting matter and become millisecond pulsars. They
can no longer be considered isolated self powered by either rotation or
latent heat.
/*---------------------------------------------------------------------*/
Intermittently Flowing Rivers of Magnetic Flux
Computer simulated trajectories of east votices moving in superconductor
with pinning sites. STrong pinning produces a few vortex channels with
heavy traffic, weak pinning induces a different network of much broader
vortex trails. The vortex channels also become wider at higher
temperatures, when pinning is weaker.